La chromatographie en phase supercritique (SFC ou CPS) est une méthode de chromatographie utilisant un fluide supercritique comme phase mobile. La SFC. CHROMATOGRAPHIE FLUIDE SUPERCRITIQUE [1 record] Technique in which the mobile phase (fluid) is maintained at temperatures. 30 sept. Analyse chirale en chromatographie en phase supercritique: méthode et applications. Journées de la section régionale de la Société.
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Run your small scale chiral purification and analysis in a single, easy-to-use platform. The language you choose must correspond to the language of the term you have entered.
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Whether you’re just looking to analyze chiral compounds or chromatogralhie to purify those compounds, Waters has the solution that fits your needs. Metrics Show article metrics. SFC excels at separating and purifying chiral compounds and natural products because it’s faster, uses much less solvent, and overall is a less expensive phasse greener method that exceeds high pressure liquid chromatography HPLC in performance for chiral separations.
As a high pressure liquid, or supercritical supedcritique, using CO 2 is a smart solvent for its low viscosity and high diffusivity needed in today’s demanding purification labs and also a sustainable solvent as it is reused after being discarded from other industrial processes.
Previous article Next article. Glossaries and vocabularies Access Translation Bureau glossaries and vocabularies. Informatique de Laboratoire et Logiciels. Guides pratiques Aide interactive pour SPE. The mobile phases used in SFC are gases such as freon, ethylene, or carbon dioxide. Download or order your copy today.
Supercritical Fluid Chromatography : Waters
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A Greener Approach to Analytical and Purification Applications For laboratories overwhelmed with solvent disposal and time-consuming solvent cleanup, supercritical fluid chromatography SFC is a beneficial alternative to purification and analytical applications. Services Articles citing this article CrossRef A collection of writing tools that cover the many facets of English and French grammar, style and usage.
Thus, SFC could be the tool chromatogrqphie choice for better determination of conversion in heavy petroleum-fraction processing. Once the optimal mobile phase and stationary phase are determined from screening, the method can be easily scaled for purification on the same system. Initial download of the metrics may take a while. Blogging About What’s Possible Read and follow the Waters blog for insights on how to use — and how customers use — our technologies, including Empower Considered a leading “green” purification technology, SFC systems from Waters are used to separate and isolate chiral and achiral chemical compounds using various methods of detection.
IFP, 62 1 Abstract. Through a calibration curve relating the boiling point of normal paraffins to their elution temperature or retention time, simdist provides the hydrocarbon distribution of the sample in weight percent versus the boiling range of the fraction.
Chromatographie liquide en ph Supervritique the application note.
Supercritical Fluid Chromatography
For laboratories overwhelmed with solvent disposal and time-consuming solvent cleanup, supercritical fluid chromatography SFC is a beneficial alternative to purification and analytical applications. The operating conditions used for simdist are tuned to be in agreement with preparative distillation that gives the True Boiling Point TBP curve. These systems easily allow you to purify a chromatographei amount of one sample. FAQ Frequently asked questions Display options.
Related Articles Group-type separation and simulated distillation: MS Imaging for Biomedical Research Understand molecular visualization and spatial distribution of compounds. Bertoncini 2 and D. The principles of SFC are similar to those of liquid chromatography, however SFC typically uses carbon dioxide as the main mobile phase. This paper presents recent advances in Simdist using SFC of heavy fractions.
It enables chromatographei automated instrument control, SFC methods development, and sample purification. Dahan 1D. Why chromatoyraphie them the same? Simulated distillation simdist based on separation using gas chromatography GC is widely spread in the petroleum industry for evaluation of fossil fuels as well as petroleum feeds and cuts produced by refining and conversion processes.
We ask, “how’d you do it? Search Waters KnowledgeBase – find answers to your troubleshooting questions. SFC is essentially a normal-phase chromatographic technique with inherent high speed and efficiency due to its mobile phase.
Practical Approaches to Peptide Isolation. Dulaurent 1L. Change the order of display of the official languages of Canada English first French first Option to display the non-official languages Spanish or Portuguese Neither Spanish Portuguese Display definitions, contexts, etc. Empower tip-of-the-week blog and newsletter. Article Abstract PDF Ask the Column Coach: The interest of supercritical-fluid chromatography SFC is that high temperatures are not needed to elute heavy ends and that the mechanism for extending the upper limit of simdist depends only on sample solubility into the supercritical mobile phase.